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which the incident radiation may couple. These dipoles can absorb energy from the incident radiation, reaching a maximum coupling with the radiation when the frequency is equal to the fundamental vibrational mode of the molecular dipole (e.g. Si-O bond) in the far-infrared, or one of its harmonics.

The selective absorption of infrared (IR) light by a particular material occurs because the selected frequency of the light wave matches the frequency (or an integral multiple of the frequency) at which the particles of that material vibrate. Since different atoms and molecules have different natural frequencies of vibration, they will selectively absorb different frequencies (or portions of the spectrum) of infrared (IR) light.

Reflection and transmission of light waves occur because the frequencies of the light waves do not match the natural resonant frequencies of vibration of the objects. When IR light of these frequencies strikes an object, the energy is either reflected or transmitted.

Manufacturing Materials

Glass optical fibers are almost always made from silica, but some other materials, such as fluorozirconate, fluoroaluminate, and chalcogenide glasses, are used for longer-wavelength infrared applications. Like other glasses, these glasses have a refractive index of about 1.5. Typically the difference between core and cladding is less than one percent.

Plastic optical fibers (POF) are commonly step-index multi-mode fibers with a core diameter of 0.5 millimeters or larger. POF typically have higher attenuation coefficients than glass fibers, 1 dB/m or higher, and this high attenuation limits the range of POF-based systems.

Silica

Tetrahedral structural unit of silica (SiO

2 ).

The amorphous structure of glassy silica (SiO

2 ). No long-range order is present, however there is local ordering with respect to the tetrahedral arrangement of oxygen (O) atoms around the silicon (Si) atoms.

Silica exhibits fairly good optical transmission over a wide range of wavelengths. In the near-infrared (near IR) portion of the spectrum, particularly around 1.5 μm, silica can have extremely low absorption and scattering losses of the order of 0.2dB/km. A high transparency in the 1.4-μm region is achieved by maintaining a low concentration of hydroxyl groups (OH). Alternatively, a high OH concentration is better for transmission in the ultraviolet (UV) region.

Silica can be drawn into fibers at reasonably high temperatures, and has a fairly broad glass transformation range. One other advantage is that fusion splicing and cleaving of silica fibers is relatively effective. Silica fiber also has high mechanical strength against both pulling and even bending, provided that the fiber is not too thick and that the surfaces have been well prepared during processing. Even