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« Previous Page Table of Contents Next Page »they will fail to excite the upper laser level. Typically reported optimum values are in the range of 80 to 100 eV per Torr·cm pressure of nitrogen gas.
There is a 40 ns upper limit of laser lifetime at low pressures and the lifetime becomes shorter as the pressure increases. The lifetime is only 1 to 2 ns at 1 atmosphere. In general
The strongest lines are at 337.1 nm *wavelength in the ultraviolet. Other lines have been reported at 357.6 nm, also ultraviolet. This information refers to the second positive system of molecular nitrogen, which is by far the most common. No vibration of the two nitrogen atoms is involved, because the atom-atom distance does not change with the electronic transition. The rotation needs to change to deliver the angular momentum of the photon, furthermore multiple rotational states are populated at room temperature. There are also lines in the far-red and infrared from the first positive system, and a visible blue laser line from the molecular nitrogen positive (1+) ion.
The metastable lower level lifetime is 40 μs, thus, the laser self-terminates, typically in less than 20 ns. This type of self-termination is sometimes referred to as “bottlenecking in the lower level”. This is only a rule of thumb as is seen in many other lasers: The helium-neon laser also has a bottleneck as one decay step needs the walls of the cavity and this laser typically runs in continuous mode. Several organic dyes with upper level lifetimes of less than 10 ns have been used in continuous mode. The Nd:YAG laser has an upper level lifetime of 200 µs, yet it also supports 100 ps pulses.
Repetition rates can range as high as a few kHz, provided adequate gas flow and cooling of the structure are provided. Cold nitrogen is a better medium than hot nitrogen, and this appears to be part of the reason that the pulse energy and power drop as the repetition rate increases to more than a few pulses per
second. There are also, apparently, issues involving ions remaining in the laser channel.
Air, which is 78% nitrogen, can be used, but more than 0.5% oxygen poisons the laser.
Optics
Nitrogen lasers can operate within a resonator cavity, but due to the typical gain of 2 every 20 mm they more often operate on superfluorescently alone, though it is common to put a mirror at one end such that the output is emitted from the opposite end.
For a 10 mm wide gain volume diffraction comes into play after 30 m along the gain medium, a length which is unheard of. Thus this laser does not need a concave lens or refocusing lenses and beam quality improves along the gain medium. The height of the pumped volume may be as small as 1 mm, needing a refocusing lens already after 0.3 m. A simple solution is to use rounded electrodes with a large radius, so that a quadratic pump profile is obtained.
Electrical
The gain medium is usually pumped by a transverse electrical discharge. When the pressure is at (or above) 1013 mbar (atmospheric pressure), the configuration is called a TEA laser T ransverse E lectrical discharge in gas at A tmospheric pressure, this is also used for pressures down to 30 mbar.
Microscopic description of a fast discharge
In a strong external electric field this electron creates an electron avalanche in the direction of the electric field lines. Diffusion of electrons and elastic scattering at a buffer gas molecule spreads the avalanche perpendicular to the field. Inelastic scattering creates photons, which create new avalanches centimeters away. After some time the electric charge in the avalanche becomes so large that following Coulomb's law it generates an electric field as large as the external electric field. At regions of increased field strength the avalanche effect is enhanced. This leads to
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